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"The world is really so surreal these days that it's necessary for us to blunt it somehow in order to stay sane. The artist functions to short-circuit the buffering mechanism, so that people can occasionally perceive the weirdness of things as they are." 
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   Although Brin did not coin the word "unobtainium" he might well be the first user of it in science fiction. See the discussion below. 
 The best guesses as to the origin of the word place it in the field of aerospace, which has been pushing the envelope in the field of materials science for at least a century.
 
As reported in the Marshall Evening Chronicle (Marshall, Michigan) on February 27, 1956:
 
 
However, it can be found even earlier in a 1930 German work "Dechema-Monographium Vol 39 page 12 link:
 
 
[Google Translate: ...Weight equal to zero. An American has jokingly called this material once the element "Unobtainium".]
 
The earliest reference to something like this (that is, a humorous name for a material that does not exist) is as far as I know "Bolognium" from Transactions of Amer Soc for Steel Treating, by Edgar Bain, in 1926.
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 Science Fiction 
        Timeline 
	    Liuzhi Process Now In Use In China 'He was in a high-ceilinged windowless cell with walls of glittering white porcelain.' 
 
	    Reflect Orbital Offers 'Sunlight on Demand' And Light Pollution 'I don't have to tell you about the seven two-mile-diameter orbital mirrors...' 
 
	    Will Robots Become Family Caregivers? 'The robant and the tiny old woman entered the control room slowly...' 
 
	    Chinese Tokamak Uses AI To Keep Fusion Plasma Stable 'Guy named Otto Octavius winds up with eight limbs... What are the odds?' 
 
	    Time Crystals Can Now Be Seen Directly 'It is as you thought when you constructed the time crystal, my master Vaylan.' 
 
	    Chrysalis Generation Ship to Alpha Centauri 'This was their world, their planet — this swift-traveling, yet seemingly moveless vessel.' 
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