The wedding took place at the Tokyo Institute of Technology; live human guests were in attendance, along with an MC and a priest. See Sal and Nene get hitched in the following video:
(Sal9000 marries Nene Anegasaki video)
Science fiction fans are not entirely unprepared for the sight of a real person marrying an anime character, thanks to the works of writers like William Gibson. He popularized the idea of a relationship with a virtual person in his 1996 novel Idoru, in which a virtual person, an idoru or idol-singer, seems so real to fans that some of them want to marry her.
Poul Anderson's 'Brain Wave'
"Everybody and his dog, it seemed, wanted to live out in the country; transportation and communication were no longer isolating factors." - Poul Anderson, 1953.
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A System To Defeat AI Face Recognition
'...points and patches of light... sliding all over their faces in a programmed manner that had been designed to foil facial recognition systems.'
Smart TVs Are Listening!
'You had to live -- did live, from habit that became instinct -- in the assumption that every sound you made was overheard...'