The wedding took place at the Tokyo Institute of Technology; live human guests were in attendance, along with an MC and a priest. See Sal and Nene get hitched in the following video:
(Sal9000 marries Nene Anegasaki video)
Science fiction fans are not entirely unprepared for the sight of a real person marrying an anime character, thanks to the works of writers like William Gibson. He popularized the idea of a relationship with a virtual person in his 1996 novel Idoru, in which a virtual person, an idoru or idol-singer, seems so real to fans that some of them want to marry her.
Humans Love Helping Other Species
'At the ringside opposite them a table had been removed to make room for a large transparent plastic capsule on wheels.' - Robert Heinlein, 1951.
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Humanoid Robots Building Humanoid Robots
''Pardon me, Struthers,' he broke in suddenly... 'haven't you a section of the factory where only robot labor is employed?''
Stratospheric Solar Geoengineering From Harvard
'Pina2bo would have to operate full blast for many years to put as much SO2 into the stratosphere as its namesake had done in a few minutes.'