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"We are all repositories for genetically-encoded information that we're all spreading back and forth amongst each other, all the time. We're just lousy with information."
- Neal Stephenson

Synthetic Spider Silk  
  Artificial fabric thread as strong as steel.  

A roofed enclosure is under construction on an asteroid; the fabric will be like a tent over a small valley.

Libby concentrated for an instant, then looked puzzled. "But look -- This valley is a thousand feet long and better than five hundred wide. At half of fifteen pounds per square inch, and allowing for the arch of the roof, that's a load of one and an eighth billion pounds. What fabric can take that kind of a load?"

"Cobwebs."

"Cobwebs?"

"Yeah, cobwebs. Strongest stuff in the world, stronger than the best steel. Synthetic spider silk, This gauge we're using for the roof has a tensile strength of four thousand pounds a running inch."

Technovelgy from Misfit, by Robert Heinlein.
Published by Astounding Science Fiction in 1939
Additional resources -

Ordinary spider silk is very tough; it is a protein fiber that has a tensile strength comparable to that of high-grade steel and about half that of fibers like Kevlar. Efforts to make garments with it date back to 1709 (if not earlier), when gloves woven from spider silk were presented to the Academy of Science in Paris.

I can't find any clear evidence that synthetic spider silk as described by Heinlein was sought prior to the publication of the story in 1940. There have been recent attempts to create artificial or synthetic spider silk:

In 2000 Canadian biotechnology company Nexia successfully produced spider silk protein in transgenic goats which carried the gene for it; the milk produced by the goats contained significant quantities of the protein, 12 grams of silk proteins per liter of milk. Attempts to spin the protein into a fiber similar to natural spider silk resulted in fibers with tenacities of 23 grams per denier...
(From Spider Silk)

Weaving with silk from silkworms is at least 5,000 years old and silkworms have been bred for much of that time.

Compare to silksteel from Alpha Centauri (1990) by Sid Meier and Plasto-textile from Foundation (1951) by Isaac Asimov. Also, see goat/spider silk from Oryx and Crake (2003) by Margaret Atwood.

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Additional resources:
  More Ideas and Technology from Misfit
  More Ideas and Technology by Robert Heinlein
  Tech news articles related to Misfit
  Tech news articles related to works by Robert Heinlein

Synthetic Spider Silk-related news articles:
  - 'Smart Silk' In Quantity
  - Artificial Spider Silk
  - Thin Film Dome Protects Cities From Nuclear Blasts

Articles related to Material
Goldene - A Two-Dimensional Sheet Of Gold One Atom Thick
GNoME AI From DeepMind Invents Millions Of New Materials
Omniphobic Liquid-like Surfaces And de Camp's Telelubricator (1940)
MXenes - Atomic-Thin Metal Sheets Now Easier To Make

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