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"Science fiction writers foresee the inevitable, and although problems and catastrophes may be inevitable, solutions are not."
- Isaac Asimov

Flexible Armor Suit  
  A pressure suit that, while flexible, becomes rigid like armor upon impact.  

As far as I know, the earliest science fiction reference for this idea.

He [Nessus the puppeteer] went up a rise, moving slowly, though his feet wanted to dance. He was weaponless, but his suit was a kind of defense. No projectile short of a fast meteorite could harm him. Like a silicone plastic, the pressure suit was soft and malleable under gentle pressures, such as walking, but instantly became rigid all over when something struck it...

The top of the swell behind Nessus suddenly sparkled with harsh blue-white sunlight. ... He saw the light, he curled into a ball, and the ground swell came. It batted him like a beach ball. His rigid, form-fitting shell retained his shape. It could not prevent the ground swell from slamming him away, nor his brain from jarring under its thick skull and its extra padding.

Technovelgy from Neutron Star, by Larry Niven.
Published by Worls of If in 1966
Additional resources -

This is from "The Soft Weapon" (originally published in Worlds of If, February, 1967) from the Neutron Star story collection.

Niven makes use of this idea again in The Ringworld Engineers:

Louis and Chmeee donned impact armor: leathery stuff, not unpleasantly stiff, which would go rigid as steel under impact from spear, arrow, or bullet...

The soldiers were close, but Filistranorlry was standing back and firing his pistol. The roar was disconcerting, even terrifying. A slug slammed into Louis's ankle; the suit went rigid, and he rolled like a tumbled statue, picked himself up, and ran again. As two soldiers threw themselves at him, he swung over the fence and dropped.

Another example of this idea, this time from March Upcountry (2001) by John Ringo and David Weber:

One of the pack beasts’ tails had hit her hard enough to harden her chameleon armor and throw her ten meters through the air and into a tree. She spun around in place and immediately spotted the bellowing carnivore that had started the ruckus.

Thanks to a helpful reader for providing the reference and text quote for Niven.

Compare to the karatand from Stand on Zanzibar (1968) by John Brunner.

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Additional resources:
  More Ideas and Technology from Neutron Star
  More Ideas and Technology by Larry Niven
  Tech news articles related to Neutron Star
  Tech news articles related to works by Larry Niven

Flexible Armor Suit-related news articles:
  - Liquid Armor In Two Flavors: Shear Thickening and Magnetorheological
  - d3o Design Competition To Invent The Future
  - Liquid Armor Video Shows Bullets Bounce Off
  - Richard Palmer, d3o Inventor, O2 X Entrepreneur of the Year
  - DEFLEXION Apparel For Superheroes
  - BAE System 'Bullet Proof Custard' Body Armor
  - Love That Shear Thickening Fluid Body Armor
  - Liquid Body Armor For TALOS Exoskeleton

Articles related to Armor
Liquid Body Armor For TALOS Exoskeleton
DIY Taser-Proof Clothing
Look Great In Your Garrison Bespoke Bulletproof Suit
Bionic Body Armor Makes You Dodge Bullets

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