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"Science fiction has gotten more accurate as we've gotten closer to the present, because science fiction stories have not only attracted, but also generated current scientists."
- Larry Niven

Impervium  
  Unique material is impenetrable and indestructible.  

A half mile beneath the shallow Venusian sea the black impervium dome that protects the Montana Keep rests frowningly on the bottom.
From Clash by Night, by Lawrence O'Donnell.
Published by Astounding Science-Fiction in 1943
Additional resources -

Impervium joins a long line of science-fictional materials the properties of which you can guess by their names: consider Steelonium from Hugo Gernsback's 1911 classic Ralph 124c 41 +, Plasteel from Frank Herbert's 1965 novel Dune and Helio-Beryllium from Robert H. Wilson's 1931 story Out Around Rigel.

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Additional resources:
  More Ideas and Technology from Clash by Night
  More Ideas and Technology by Lawrence O'Donnell
  Tech news articles related to Clash by Night
  Tech news articles related to works by Lawrence O'Donnell

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