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"...science fiction is sort of like a sociological genome. It's a huge range of possible futures, most of them useless; some vital. You never really know in advance."
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Although Brin did not coin the word "unobtainium" he might well be the first user of it in science fiction. See the discussion below.
The best guesses as to the origin of the word place it in the field of aerospace, which has been pushing the envelope in the field of materials science for at least a century.
As reported in the Marshall Evening Chronicle (Marshall, Michigan) on February 27, 1956:
However, it can be found even earlier in a 1930 German work "Dechema-Monographium Vol 39 page 12 link:
[Google Translate: ...Weight equal to zero. An American has jokingly called this material once the element "Unobtainium".]
The earliest reference to something like this (that is, a humorous name for a material that does not exist) is as far as I know "Bolognium" from Transactions of Amer Soc for Steel Treating, by Edgar Bain, in 1926.
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