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"The immediate problem with our meat brains is that they have no back-up. We can lose the most precious information we have from one bump on the head or stroke. You want a mind system with back-up that can access other databases."
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Although Brin did not coin the word "unobtainium" he might well be the first user of it in science fiction. See the discussion below.
The best guesses as to the origin of the word place it in the field of aerospace, which has been pushing the envelope in the field of materials science for at least a century.
As reported in the Marshall Evening Chronicle (Marshall, Michigan) on February 27, 1956:
However, it can be found even earlier in a 1930 German work "Dechema-Monographium Vol 39 page 12 link:
[Google Translate: ...Weight equal to zero. An American has jokingly called this material once the element "Unobtainium".]
The earliest reference to something like this (that is, a humorous name for a material that does not exist) is as far as I know "Bolognium" from Transactions of Amer Soc for Steel Treating, by Edgar Bain, in 1926.
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